WebDavid A Nagib A cross-selective aza-pinacol coupling of aldehydes and imines has been developed to afford valuable β-amino alcohols. This strategy enables chemoselective conversion of aliphatic... WebDec 8, 2011 · David Nagib and David MacMillan report a new method for this synthesis that is more economical than current methods in terms of both raw materials and energy …
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WebJun 22, 2024 · Ethan A. Wappes, Leah M. Stateman, Andrew D. Chen & David A. Nagib Nature Chemistry 12 , 697–704 ( 2024) Cite this article 32k Accesses 94 Citations 180 Altmetric Metrics Abstract Asymmetric,... WebOct 12, 2024 · Combination of the resultant ketyl radical 7 with alkyne 8 affords vinyl radical 9. This open-shell intermediate is formally oxidized by Mn (CO) 5 I ( 10, [Mn]-I) via atom transfer to regenerate the Mn• catalyst ( 5 ), while also forming vinyl iodide 3 ′ in a redox-neutral mechanism ( 32 ). The net conversion of 6 to 3 ′ is exothermic ... shoprider battery charger
Trifluoromethylation of arenes and heteroarenes by …
WebMay 23, 2011 · A facile and efficient method for the α-trifluoromethylation of carbonyl compounds and enolsilanes has been accomplished through application of a photoredox catalysis strategy. A one-flask procedure ... WebWe had the pleasure of presenting to HEC Paris and ESSEC Business School students about the exciting career opportunities available at Accenture Strategy It… 19 commentaires sur LinkedIn WebD. A. Nagib, D. W. C. MacMillan Science, 334, 1114-1117 Discovery of an α -Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity shoprider battery pack